Time-resolved infrared spectra were recently collected via a Fourier-transform spectrometer (FTS) from the detonation fireballs of two types of conventional military munitions (CMM) as well as uncased TNT and four types of enhanced novel explosives (ENEs). The CMM spectra are dominated by continuum emission, and a single-temperature Planckian distribution, modified for atmospheric attenuation, captures most of the variation in the data. Some evidence of selective emission is identified by systematic patterns in the fit residuals. The behavior of these systematic residuals affords a distinction between the two types of CMMs studied. The uncased TNT and ENE spectra appear strongly influenced by both continuum and selective emission. A physics-based spectral model is developed consisting of seven parameters: size, temperature, particulate absorption coefficient, and gas concentrations for H2O, CO2, CO, and HCl. Fitting affords a high-fidelity representation with features that correlate with HE characteristics.