Rh(III) and Ir(III) catalyzed C-C bond cross couplings from C-H bonds.- Rh(III) and Ir(III)-catalyzed C-H bond transformations into C-N, C-O and C-X bonds.- Copper mediated C-H/C-H and C-H/N-H couplings.- Iron-catalyzed C-H Bond Activation.- Nickel-catalyzed C-H bond functionalization.- meta- and para-selective C-H bond functionalization by C-H metalation.- Catalytic C-H bond functionalization of cyclopropane derivatives.- Silver-Mediated Direct sp3 C-H Transformations.- Applications of catalytic organometallic C(sp3)-H Bondfunctionalization.- New concepts of C-H and C-C bond activation via surface organometallic chemistry.- Catalytic activation of alkanes with Pincer Catalysts.